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101.
Wei‐Guang Shan Zai‐Lin Gao You‐Min Ying Jia‐Gui Xiang Fa‐Song Wang Zha‐Jun Zhan 《Helvetica chimica acta》2014,97(11):1526-1530
Two new tirucallane‐type triterpenoids, (24Z)‐tirucalla‐7,24‐diene‐3β,11β,26‐triol ( 1 ) and (3S,24R)‐tirucall‐7‐ene‐3,24,25‐triol ( 2 ), along with the known compound celastrol ( 3 ), were isolated from the root barks of Celastrus stylosus Wall . The structures of 1 – 3 were established by spectroscopic methods, including extensive 2D NMR and MS analyses. It is the first report on tirucallane‐type triterpenoids from the genus Celastrus and may be of vital chemotaxonomic significance. 相似文献
102.
Shuya. Wei Xiaoyang. Fang Xuejun. Cao Manfred Schreiner 《Journal of Analytical and Applied Pyrolysis》2011,91(1):147-153
Chinese ink stick has a long history and a special importance in Chinese culture. Its main components are soot (normally pine wood soot and lamp soot) and animal glue; however, additives were added from time to time for different purposes. In order to see whether the two types of soot can be differentiated and the other constituents in Chinese ink sticks can be identified or not by Pyrolysis-Gas Chromatography-Mass Spectrometry (Py-GC-MS) and GC-MS techniques, an initial study has been carried out. The main polycyclic aromatic hydrocarbons (PAHs) in soot could be identified, which are anthracene, fluoranthene, triphenylene and benz[e]acephenanthrylene. The main difference between those two types of soot is that the detectable amount of PAHs in lamp soot is much lower than in pine wood soot. In addition to this, the relative concentration of the main polycyclic aromatic hydrocarbons including anthracene, fluoranthene, pyrene, triphenylene and its isomer, benzo[k]fluoranthene and its isomers are different in the two types of soot. The relative content of benzo[k]fluoranthene is higher in pine soot than in lamp soot, which could be used to as a criterion to differentiate the two types of soot. Py-GC-MS technique is a very effective method to identify the main components of Chinese ink sticks, including the PAHs of soot, binding media and the additives of camphor and borneol in one analysis. 相似文献
103.
Liang W Bera T Zhang X Gesquiere AJ Fang J 《Langmuir : the ACS journal of surfaces and colloids》2011,27(3):1051-1055
Long-range organization of molecular tilt azimuth is a striking feature in monolayers at the air-water interface. We show that the boojum and stripe textures of pentadecanoic acid (PDA) with the continuous variations of molecular tilt azimuth formed at the air-water interface at temperatures lower than room temperature can be preserved after being transferred to glass substrates at low dipping speeds. The long-range tilt order in the transferred boojums and stripes is resolved by frictional force microscopy at room temperature, suggesting that the tilt order is "frozen" through the interaction of PDA molecules with the glass surface. The transferred stripe structure can be used as a unique alignment layer to induce a continuously azimuthal orientation of nematic liquid crystals. 相似文献
104.
105.
106.
Virgatolides A-C (1-3), unique metabolites with a 3',4',5',6'-tetrahydrospiro[chroman-2,2'-pyran] core, were isolated from cultures of the plant endophytic fungus Pestalotiopsis virgatula. Compounds 1-3 possess two previously undescribed skeletons originating from a benzannulated 6,6-spiroketal and one (2 and 3) and two (1) γ-lactone units, respectively. The structure of 1 was secured by X-ray crystallography. 相似文献
107.
108.
Synthesis of raspberry-like monodisperse magnetic hollow hybrid nanospheres by coating polystyrene template with Fe(3)O(4)@SiO(2) particles 总被引:1,自引:0,他引:1
A new inorganic/organic hybrid material containing silsesquioxane was prepared by the reaction of caged octa (aminopropyl silsesquioxane) (POSS-NH(2)) with n-butyl glycidyl ether (nBGE) and 1,4-butanediol diglycidyl ether (BDGE). The copolymers of POSS, nBGE, and BDGE could be obtained with varied feed ratio of POSS-NH(2), nBGE, and BDGE in the preparation. The hybrid material was added into an epoxy resin (E51) for enhancing the toughening and thermal properties of the epoxy resin. The results showed that the toughening and the thermal properties of the cured epoxy resin were greatly improved by the addition of the hybrid. The enhancement was ascribed to nano-scale effect of the POSS structure and the formation of anchor structure in the cured network. The investigation of kinetics for the curing process of the hybrid-modified epoxy resin revealed that two kinds of curing reactions occurred in different temperature ranges. They were attributed to the reactions between amino groups of the curing agent with epoxy groups of E51 and with residue epoxy groups in the hybrid. The reacting activation energies were calculated based on Kissinger's and Flynn-Wall-Ozawa's methods, respectively. 相似文献
109.
We develop a monotone finite volume method for the time fractional Fokker-Planck equations and theoretically prove its unconditional stability. We show that the convergence rate of this method is of order 1 in the space and if the space grid becomes suffciently fine, the convergence rate can be improved to order 2. Numerical results are given to support our theoretical findings. One characteristic of our method is that it has monotone property such that it keeps the nonnegativity of some physical variables such as density, concentration, etc.
相似文献110.
Let n>1 and B be the unit ball in n dimensions complex space Cn.Suppose thatφis a holomorphic self-map of B andψ∈H(B)withψ(0)=0.A kind of integral operator,composition Cesàro operator,is defined by Tφψ(f)(z)=∫10f[φ(tz)]Rψ(tz)dt/t,f∈(B)z∈B.In this paper,the authors characterize the conditions that the composition Cesàro operator T_φ,ψis bounded or compact on the normal weight Zygmund space Z_μ(B).At the same time,the sufficient and necessary conditions for all cases are given. 相似文献